In what is being billed as an "exclusive, tell-all" session, the streaming, multi-user chat service will air on Friday, Oct. 3 from 5-8 p.m. (PST).
Mary Carey is among 132 candidates, including Hustler's Larry Flynt, running to replace Governor Gray Davis in the California recall.
"We're getting her before the election date because we're sure people want to ask questions and see everything about Mary that there is to see," Tina Fiora of Video Secrets told XBiz. "What she's doing is a good boost for the porn industry. Mary has really made a name for herself. I don't think that many people had heard of her before the recall."
Among Carey's many political ambitions, she is in favor of legalizing gay marriage, taxing breast implants, making lap dances a tax deductible expense, and installing web cams in the governor's mansion.
Since tossing her hat into the gubernatorial ring the Ohio-born porn actress, who reportedly draws in a yearly income of $200,000, has seen a boom in her video sales, including sales on current films "New Wave Hookers 7" and "Grand Opening."
Carey made a recent appearance at a San Francisco trade show where she with flanked by press and fans.
"I want to show people just because I have blond hair, big boobs, and do porn that I am not dumb," Carey was quoted by Reuters as saying. "Running for governor is pretty much for me to get my ideas out there."
According to Video Secrets, Flirt4Free.com users will be able to view and chat with Carey in the group video and chat area where she will be available for flirting and soft-core requests. Carey will also perform totally nude fee-based 'Private Shows' during the Flirt4Free webcast.
The live feed will also air on Carey's website (www.marycarey.com) where the porn star is quoted as saying she wants to have sex with rival political candidate Arnold Schwarzenegger. "I think he's hot," Carey states on her website.
Video Secret's Flirt4Free service was launched in 1999 and features a rotating roster of porn actors and actresses, including porn film star Jenna Jameson and the Vivid Girls Sunrise Adams, Mercedez, and Tawny Roberts.
Flirt4Free will launch the 5.0 version of its free chat service on Oct. 8.
Porn mogul Larry Flynt also announced his candidacy for governor in August and has been operating under the slogan: "Vote for a Smut-Peddler Who Cares."
"Just because I publish pornography does not mean that I am not concerned about the social ills that all of us are," Flynt was quoted as saying.
If voted into the governor's seat, Flynt has said he will focus his political agenda on educational improvements for the State of California and expanding gaming regulations to allow private casinos to have slot machines, which could be taxed by the state at 30 percent. Flynt is also in favor of granting amnesty to all illegal immigrants.